Sabtu, 29 September 2012

petroleum


PETROLEUM

Petroleum (English: petroleum, from Latin petrus - rock and oleum - oil), also dubbed as the black gold, is a thick liquid, dark brown or greenish flammable, which is in the upper layers of the few areas in the crust earth. Petroleum consists of a complex mixture of different hydrocarbons, the majority of the alkane series, but vary in appearance, composition, and purity. Oil extracted from oil wells in the oil mines. Location of the wells is obtained after going through the process of geological studies, sediment analysis, character and structure of the source, and a variety of other studies.  After that, the Earth will be processed in oil refineries where oil and separated the results by boiling point to produce a wide range of fuels, from gasoline and kerosene to asphalt and other chemical reagents needed to make plastics and pharmaceuticals. oil is used to produce a wide variety of goods and material human needs.

composition

If seen rough, earth oil contains only crude oil, but in everyday use it is also used in the form of hydrocarbon solids, liquids, and gases. At standard temperature and pressure conditions, light hydrocarbons such as methane, ethane, propane, and butane is a gas that boils at -161.6 ° C, -88.6 ° C, -42 ° C, and -0.5 ° C, respectively (- 258.9 °, -127.5 °, -43.6 ° and +31.1 ° F), while the carbon is higher, ranging from pentane to the form of solids or liquids. Even so, in the oil under the ground, the proportion of gases, liquids, and solids depending on surface conditions and the phase diagram of the petroleum mixture Earth.

Most oil wells producing crude oil, and sometimes there is also the natural gas content in it. Since the pressure at the Earth's surface is lower than underground, some of the gas will come out in the form of a mixture. Most gas wells producing gas. However, as the temperature and pressure in the underground is greater than the temperature at the surface, the gas that comes out is sometimes also contain larger hydrocarbons, such as pentane, hexane, and heptane in the form of gas. On the surface, the gas will condense that form natural gas condensate. Physical form of condensate is similar to gasoline.

The percentage of light hydrocarbons in crude oil varies depending on the oil fields, the maximum content can be up to 97% of the gross weight and the minimum is 50%.

Types of hydrocarbons contained in the Earth's oil consists mainly of alkanes, cycloalkanes, and a variety of aromatic hydrocarbons, coupled with some other minor elements such as nitrogen, oxygen and sulfur, plus some types of metals such as iron, nickel, copper, and vanadium . The number of molecular composition vary greatly from one oil to another oil but the percentage proportion of the chemical elements can be seen below:
Petroleum is a mixture of various hydrocarbons, the type most commonly found molecules are alkanes (both straight-chain or branched), cycloalkanes, aromatic hydrocarbons, or compounds such as aspaltena complex. Each oil has a unique molecular Earth respectively, are known from the physical and chemical characteristics, color, and viscosity.

Alkanes, also called paraffins, are saturated hydrocarbons with straight or branched chain molecules containing only the elements carbon and hydrogen with the general formula CnH2n +2. In general, the Earth oil containing 5 to 40 carbon atoms per molecule, although the number of carbon molecules with fewer / more may also be present in the mixture.

Alkanes from pentane (C5H12) to octane (C8H18) are refined into gasoline, while alkanes kind nonana (C9H20) to hexadecane (C16H34) will be refined into diesel, kerosene and jet fuel). Alkanes with 16 or more carbon atoms will be refined into oil / lubricant. Alkanes with the number of carbon atoms greater, such as paraffin wax having 25 carbon atoms, and the asphalt has more than 35 carbon atoms. Alkanes with the number of carbon atoms 1 to 4 will be a gas at room temperature, and sold as LPG (LPG). In winter, butane (C4H10), used as a blend in gasoline, because of the high vapor pressure of butane will help the engine running in the winter. Another is the use of alkanes as a cigarette lighter. In some countries, propane (C3H8) can be availed under moderate pressure, and community use as a transportation fuel and cooking.

Cycloalkanes, also known as naptena, are saturated hydrocarbons which have one or more double bond in the carbon, with the general formula CnH2n. Cycloalkanes have characteristics that are similar to alkanes but have higher boiling points.

Aromatic hydrocarbons are saturated hydrocarbons which have one or more carbon-6 planar rings called benzene rings, where the hydrogen atom will bond with the carbon atom with the general formula CnHn. Such hydrocarbons when burned it will cause black smoke. Some are carcinogenic.

All kinds of different molecules above separated by fractional distillation in a refinery to produce gasoline, jet fuel, kerosene, and other hydrocarbons. An example is 2,2,4-trimethylpentanes (isooctane), was used as the main mix in gasoline, has a chemical formula C8H18 and the exothermic reaction with oxygen:

    2 C8H18 (l) + 25 O2 (g) → 16 CO2 (g) + 18 H2O (g) + 10.86 MJ / mol (of octane)

The number of each molecule on Earth oil can be studied in the laboratory. These molecules usually be extracted in a solvent, then separated in the gas chromatograph, and then can be detected by a suitable detector.

Incomplete combustion of petroleum Earth or processed products will cause toxic byproducts. For example, too little oxygen is mixed it will produce carbon monoxide. Due to the high temperature and pressure inside the engine, the exhaust gases produced by the engine is usually also contain molecular nitrogen oxides that can cause smog.

 comment
one example of oil in nature is oil . how oil is not exhausted in nature whether oil can be recycled?

and what happens if the oil is already out in the wild?





why ethylene gas causing the fruit to mature?

Ethylene is a plant hormone first in the form of gas. If the fruit is ripe oranges combined with bananas, ripe bananas are faster because oranges emit ethylene gas. The discovery of this hormone in plants first described by R. Gane in 1934.

Ethylene is a plant and cause more rapid maturation in many fruits, including bananas. Ethylene formation requires O2 and is inhibited by CO2. All parts of the plant can produce ethylene gas angiosperms. Formation mainly occurs in roots, shoot apical meristem, mode, fall flowers and ripe fruit.

Ethylene gas has an influence on growth and development, including the following.
1) Ripening fruit. The traders often store the fruit in containers gassed with CO2 at the time of delivery so that the fruit longer to mature and ripen after destination. Sometimes merchants brood ripe fruit with fresh fruit that mature quickly.
2) Gas ethylene inhibits flowering in many plants. However, in some plant species, ethylene stimulates flowering. For example, the mango trees and pineapples.
3) Stimulate abscission (defoliation).
4) Joint gibberellin determine the expression of the genital organs of plants, such as the cucumber.

Senin, 24 September 2012


Hydrocarbons and utilization her



In chemistry, a hydrocarbon is a compound composed of the elements carbon (C) and hydrogen atoms (H). The entire chain hydrocarbons having carbon and hydrogen atoms bonded to the chain. The term is used also as a sense of aliphatic hydrocarbons.

For example, methane (swamp gas) is a hydrocarbon with one carbon atom and four hydrogen atoms: CH4. Ethane is a hydrocarbon (more specifically, an alkane) consisting of two carbon atoms are united by a single bond, each of which binds to three carbon atoms: C2H6. Propane has three C atoms (C3H8) and beyond (CnH2 · n +2).

A major component of natural gas is methane (CH4), which is the shortest chain hydrocarbon molecules and lightest. Natural gas also contains hydrocarbon molecules heavier such as ethane (C2H6), propane (C3H8) and butane (C4H10), as well as gases that contain sulfur (sulfur). Natural gas is also a major source of helium gas source.

Methane is a greenhouse gas that can create global warming when released into the atmosphere, and is generally regarded as a pollutant rather than a useful energy source. However, methane in the atmosphere reacts with ozone, producing carbon dioxide and water, so that the greenhouse effect of methane is released into the air is relatively just a moment. Methane sources from living mostly from termites, livestock (mammals) and agriculture (estimated emissions levels of approximately 15, 75 and 100 million tonnes per year respectively).

component%
Methane (CH4) 80-95
Ethane (C2H6) 5-15
Propane (C3H8) and Butane (C4H10) <5...
Nitrogen, helium, carbon dioxide (CO2), hydrogen sulfide (H2S), and water can also be contained in natural gas. Mercury can also be found in small quantities. The composition of natural gas varies according to the source of the gas fields.

Organosulfur mixture and hydrogen sulfide are contaminants (pollutants) from the gas main to be separated. Gas with a significant amount of sulfur impurities called sour gas and is often referred to as "acid gas (sour gas)". Natural gas that has been processed and will be sold is tasteless and odorless. However, before the gas is distributed to end users, the gas is usually given odor by adding a thiol, to be detected in the event of a gas leakNatural gas that has been processed in itself is not dangerous, but without the natural gas can cause respiratory strangled because it can reduce the oxygen content in the air at levels that may be harmful.
. Natural gas can be dangerous because it is highly flammable and cause an explosion. Natural gas is lighter than air, so it tends to easily dispersed in the atmosphere. However, if he is in a confined space, such as inside the house, gas concentrations can reach explosive mixtures point, which if ignited a fire, may cause an explosion that can destroy buildings. Harmful methane content in the air is between 5% to 15%.

Explosion for compressed natural gas in vehicles, generally do not worry because it is lighter, and the concentration outside the range of 5-15% which can cause an explosion.
Types of hydrocarbons
Classification of hydrocarbons, which are grouped by organic nomenclature is:
1. Hydrocarbon saturated / saturated (alkanes) are the simplest hydrocarbon. Hydrocarbons is composed entirely of a single bond and bound with hydrogen. The general formula for saturated hydrocarbons is CnH2n 2. [1] is the main composition of saturated hydrocarbons in fossil fuels and is found in the form of straight or branched chain. Hydrocarbons with the same molecular formula but different structural formulas called structural isomers. [2]
2. Unsaturated hydrocarbons / is not saturated hydrocarbons which have one or more double bonds, either duplicate or triplicate. Hydrocarbons having double bonds called alkenes, with the general formula CnH2n. [3] hydrocarbons that have a triple bond are called alkynes, with general formula CnH2n-2. [4]
3. Cycloalkanes are hydrocarbons containing one or more carbon rings. The general formula for saturated hydrocarbons is CnH2n ring with 1. [2]
4. Aromatic hydrocarbons, also known as the arena, are hydrocarbons that have at least one aromatic ring.

hydrocarbons


Hydrocarbons and utilization her



In chemistry, a hydrocarbon is a compound composed of the elements carbon (C) and hydrogen atoms (H). The entire chain hydrocarbons having carbon and hydrogen atoms bonded to the chain. The term is used also as a sense of aliphatic hydrocarbons.

For example, methane (swamp gas) is a hydrocarbon with one carbon atom and four hydrogen atoms: CH4. Ethane is a hydrocarbon (more specifically, an alkane) consisting of two carbon atoms are united by a single bond, each of which binds to three carbon atoms: C2H6. Propane has three C atoms (C3H8) and beyond (CnH2 · n +2).

A major component of natural gas is methane (CH4), which is the shortest chain hydrocarbon molecules and lightest. Natural gas also contains hydrocarbon molecules heavier such as ethane (C2H6), propane (C3H8) and butane (C4H10), as well as gases that contain sulfur (sulfur). Natural gas is also a major source of helium gas source.

Methane is a greenhouse gas that can create global warming when released into the atmosphere, and is generally regarded as a pollutant rather than a useful energy source. However, methane in the atmosphere reacts with ozone, producing carbon dioxide and water, so that the greenhouse effect of methane is released into the air is relatively just a moment. Methane sources from living mostly from termites, livestock (mammals) and agriculture (estimated emissions levels of approximately 15, 75 and 100 million tonnes per year respectively).

component%
Methane (CH4) 80-95
Ethane (C2H6) 5-15
Propane (C3H8) and Butane (C4H10) <5...
Nitrogen, helium, carbon dioxide (CO2), hydrogen sulfide (H2S), and water can also be contained in natural gas. Mercury can also be found in small quantities. The composition of natural gas varies according to the source of the gas fields.

Organosulfur mixture and hydrogen sulfide are contaminants (pollutants) from the gas main to be separated. Gas with a significant amount of sulfur impurities called sour gas and is often referred to as "acid gas (sour gas)". Natural gas that has been processed and will be sold is tasteless and odorless. However, before the gas is distributed to end users, the gas is usually given odor by adding a thiol, to be detected in the event of a gas leakNatural gas that has been processed in itself is not dangerous, but without the natural gas can cause respiratory strangled because it can reduce the oxygen content in the air at levels that may be harmful.
. Natural gas can be dangerous because it is highly flammable and cause an explosion. Natural gas is lighter than air, so it tends to easily dispersed in the atmosphere. However, if he is in a confined space, such as inside the house, gas concentrations can reach explosive mixtures point, which if ignited a fire, may cause an explosion that can destroy buildings. Harmful methane content in the air is between 5% to 15%.

Explosion for compressed natural gas in vehicles, generally do not worry because it is lighter, and the concentration outside the range of 5-15% which can cause an explosion.
Types of hydrocarbons
Classification of hydrocarbons, which are grouped by organic nomenclature is:
1. Hydrocarbon saturated / saturated (alkanes) are the simplest hydrocarbon. Hydrocarbons is composed entirely of a single bond and bound with hydrogen. The general formula for saturated hydrocarbons is CnH2n 2. [1] is the main composition of saturated hydrocarbons in fossil fuels and is found in the form of straight or branched chain. Hydrocarbons with the same molecular formula but different structural formulas called structural isomers. [2]
2. Unsaturated hydrocarbons / is not saturated hydrocarbons which have one or more double bonds, either duplicate or triplicate. Hydrocarbons having double bonds called alkenes, with the general formula CnH2n. [3] hydrocarbons that have a triple bond are called alkynes, with general formula CnH2n-2. [4]
3. Cycloalkanes are hydrocarbons containing one or more carbon rings. The general formula for saturated hydrocarbons is CnH2n ring with 1. [2]
4. Aromatic hydrocarbons, also known as the arena, are hydrocarbons that have at least one aromatic ring.